156094-75-6Relevant academic research and scientific papers
A radical mediated approach to the core structure of huperzine A
Ward, Jarrod,Caprio, Vittorio
, p. 553 - 556 (2006)
The synthesis of the core structure of huperzine A by cyclisation of 2-pyridylmethyl radicals is described. (2-Methylpyridin-3-yl)cyclohexenols are directly selenated at the benzylic position by deprotonation/selenation and the products undergo either 5-e
Functionalisation of 2-methoxy-6-methylpyridine
Gray,Konopski,Langlois
, p. 1367 - 1379 (2007/10/02)
Selective bromination of 2-methoxy-6-methylpyridine 2 afforded 5-bromo-2- methoxy-6-methylpyridine 8. Deprotonation of this pyridine derivative in benzylic position or lithium-bromine exchange allowed the regio-selective introduction of various electrophiles.
