1561-50-8Relevant academic research and scientific papers
Relative Rate Constants for the Reactions of CF3OF with Olefins in Solution
Navarrini, W.,Russo, A.,Tortelli, V.
, p. 6441 - 6443 (2007/10/03)
The addition reactions of CF3OF to chloro fluoro olefins have been studied in solution at low temperature (-78, -105 deg C), and their relative rate constants have been determined using the kinetic approach of competition reactions.The reactivity and regio- and stereoselectivity are consistent with a free radical chain-propagating reaction in which the alkenes are attacked by the CF3O* radical generated by homolytic cleavage of the O-F bond in the CF3OF molecule.
Fluorination of Chlorinated Trifluoromethyl Ethers
Sekiya, Akira,Ueda, Kunimasa
, p. 1421 - 1424 (2007/10/02)
Chlorine atoms in the chlorinated trifluoromethyl ether prepared from the reaction between chlorinated ethylenes and trifluoromethyl hypofluorite were fluorinated directly by fluorine gas.Tin(II) fluoride/sodium fluoride system was effective in the fluorination.
