1561041-07-3Relevant academic research and scientific papers
Gold(i)-catalysed [1,3] O→C rearrangement of allenyl ethers
Kona, Chandrababu Naidu,Ramana, Chepuri V.
supporting information, p. 2152 - 2154 (2014/02/14)
A simple and rapid access to the α-substituted acryl aldehydes has been provided by developing a gold-catalysed [1,3] rearrangement of the allenyl ethers importantly with a record turnover frequency of 4600 h-1 (at 0.05 mol% of the catalyst concentration) in homogeneous gold(i) catalysis. The Royal Society of Chemistry.
