156220-42-7

Basic information

• Product Name: (CO)5Cr(CH₃OC₆H₄S(O)CH₃)
• CAS NO: 156220-42-7
• Molecular Weight: 362.28
• Mol File: 156220-42-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (CO)5Cr(CH₃OC₆H₄S(O)CH₃)(CAS DataBase Reference)
• NIST Chemistry Reference: (CO)5Cr(CH₃OC₆H₄S(O)CH₃)(156220-42-7)
• EPA Substance Registry System: (CO)5Cr(CH₃OC₆H₄S(O)CH₃)(156220-42-7)

Safety Data

• Hazardous Substances Data: 156220-42-7(Hazardous Substances Data)

Upstream product

• 27792-49-0 tricarbonyltrispyridinechromium⁽⁰⁾ 
• 274928-75-5 1-methanesulfinyl-3-methoxy-benzene 
• 16800-46-7 trisacetonitrile(tricarbonyl)chromium⁽⁰⁾ 

Relevant articles and documents

Oxidation of Alkylthio Substituted Tricarbonyl(η6-arene)chromium(0) Complexes to Alkylsulfinyl Substituted Tricarbonyl(η6-arene)chromium(0) Complexes

Dimethyldioxirane efficiently oxidises tricarbonylchromium(0) complexes of alkylthio substituted arenes to tricarbonylchromium(0) complexes of alkylsulfinyl substituted arenes.The diastereoselectivity of oxidation of ortho substituted complexes, which was determined by inter alia X-ray crystal structure analyses of tricarbonyl6-1-methoxy-2-(methylsulfinyl)benzene>-chromium(0) 20x, 6-1-(tert-butylsulfinyl)-2-methoxybenzene>tricarbonylchromium(0) 23x and tricarbonyl6-1-(ethylsulfinyl)-2-methoxybenzene)chromium(0) 21y, is dependent on the alkylthio substituent and is reversed when this substituent is changed from methylthio to tert-butylthio.