1562407-85-5Relevant academic research and scientific papers
Cobalt(III)-catalyzed fast and solvent-free C-H allylation of indoles using mechanochemistry
Jiang, Xinpeng,Chen, Jinkang,Zhu, Weijie,Cheng, Kang,Liu, Yong,Su, Wei-Ke,Yu, Chuanming
, p. 10665 - 10672 (2018/05/31)
Mechanochemical conditions have been applied to a highly efficient cobalt(III)-catalyzed C-H bond activation for the first time. In a subsequent step to the olefin insertion and β-oxygen elimination, N-pyrimidinylindoles were allylated with vinylethylene carbonates in the absence of organic solvent under high-speed ball-milling condition. As the reaction afforded the desired products in up to 98% yields within a short time, this method constitutes an environmentally friendly and powerful alternative to the common solution-based approaches.
Rhodium-catalyzed mild and selective C-H allylation of indolines and indoles with 4-vinyl-1,3-dioxolan-2-one: Facile access to indolic scaffolds with an allylic alcohol moiety
Sharma, Satyasheel,Shin, Youngmi,Mishra, Neeraj Kumar,Park, Jihye,Han, Sangil,Jeong, Taejoo,Oh, Yongguk,Lee, Youngil,Choi, Miji,Kim, In Su
, p. 2435 - 2441 (2015/03/04)
Abstract The rhodium(III)-catalyzed selective C-H allylations of indolines and indoles with 4-vinyl-1,3-dioxolan-2-one at room temperature are described. These transformations provide the direct and efficient formation of indolic scaffolds containing an a
Mild rhodium(III)-catalyzed C-H allylation with 4-vinyl-1,3-dioxolan-2-ones: Direct and stereoselective synthesis of (E)-allylic alcohols
Zhang, Shang-Shi,Wu, Jia-Qiang,Lao, Ye-Xing,Liu, Xu-Ge,Liu, Yao,Lv, Wen-Xin,Tan, Dong-Hang,Zeng, Yao-Fu,Wang, Honggen
supporting information, p. 6412 - 6415 (2015/01/09)
A rhodium(III)-catalyzed C-H direct allylation reaction with 4-vinyl-1,3-dioxolan-2-ones has been developed. The reaction provides a facile and stereoselective access to substituted-(E)-allylic alcohols under mild and redox-neutral reaction conditions. Olefinic C-H activation is applicable, giving multifunctionalized skipped dienes in good yields. Minimal double-bond migration was observed.
