1562407-91-3Relevant academic research and scientific papers
Cobalt(III)-catalyzed fast and solvent-free C-H allylation of indoles using mechanochemistry
Jiang, Xinpeng,Chen, Jinkang,Zhu, Weijie,Cheng, Kang,Liu, Yong,Su, Wei-Ke,Yu, Chuanming
, p. 10665 - 10672 (2017)
Mechanochemical conditions have been applied to a highly efficient cobalt(III)-catalyzed C-H bond activation for the first time. In a subsequent step to the olefin insertion and β-oxygen elimination, N-pyrimidinylindoles were allylated with vinylethylene carbonates in the absence of organic solvent under high-speed ball-milling condition. As the reaction afforded the desired products in up to 98% yields within a short time, this method constitutes an environmentally friendly and powerful alternative to the common solution-based approaches.
Air-Stable Manganese(I)-Catalyzed C?H Activation for Decarboxylative C?H/C?O Cleavages in Water
Wang, Hui,Lorion, Mélanie M.,Ackermann, Lutz
supporting information, p. 6339 - 6342 (2017/05/22)
The decarboxylative C?H/C?O functionalization was accomplished by air- and water-tolerant manganese(I) catalysis. The versatile C?H allylation occurred by facile organometallic C?H metalation on indoles, arenes, amino acids and synthetically meaningful ar
