1562648-64-9Relevant articles and documents
Photoredox-induced three-component Oxy-, Amino-, and Carbotrifluoromethylation of enecarbamates
Carboni, Aude,Dagousset, Guillaume,Magnier, Emmanuel,Masson, Geraldine
supporting information, p. 1240 - 1243 (2014/03/21)
A photoredox-catalzyed trifluoromethylation of enecarbamates process is reported. This pathway uses Togni's reagent as the CF3 source and follows a radical/cationic pathway. Under the optimized conditions using [Ru(bpy)3(PF6)2] as the photocatalyst, a wide range of substituted enecarbamates can readily be difunctionalized by means of various O, N, and C nucleophiles.