15629-06-8

Basic information

• Product Name: trans-[PtCl₂(1,2,5-triphenylphosphole)2]
• CAS NO: 15629-06-8
• Molecular Weight: 890.687
• Mol File: 15629-06-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: trans-[PtCl₂(1,2,5-triphenylphosphole)2](CAS DataBase Reference)
• NIST Chemistry Reference: trans-[PtCl₂(1,2,5-triphenylphosphole)2](15629-06-8)
• EPA Substance Registry System: trans-[PtCl₂(1,2,5-triphenylphosphole)2](15629-06-8)

Safety Data

• Hazardous Substances Data: 15629-06-8(Hazardous Substances Data)

Upstream product

• 14873-63-3 bis(benzonitrile)dichloroplatinum(II) 
• 1162-70-5 1,2,5-triphenyl-1H-phosphole 

Relevant articles and documents

Platinum(ii)-phosphole complexes: Synthesis and evaluation as enyne cycloisomerisation catalysts

A series of platinum(ii)-monophosphole complexes has been synthesized and used in enyne cycloisomerisations in order to study the effect of the ligand on the catalytic activity and selectivity. Reactions were performed on various N- or C-tethered 1,6-enynes and in the absence or in the presence of nucleophiles. For the most efficient cationic Pt(ii)-complexes, it was also evidenced that the counterion and/or the solvent could have an influence on both the efficiency and the selectivity in the competition between the 5-exo-dig and the 6-endo-dig processes. This journal is the Partner Organisations 2014.