1563118-44-4

Basic information

• Product Name: 1-cyclopropylbenzocycyclobutenol
• Synonyms: 1-cyclopropylbenzocycyclobutenol
• CAS NO: 1563118-44-4
• Molecular Weight: 160.216
• Mol File: 1563118-44-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 1-cyclopropylbenzocycyclobutenol(CAS DataBase Reference)
• NIST Chemistry Reference: 1-cyclopropylbenzocycyclobutenol(1563118-44-4)
• EPA Substance Registry System: 1-cyclopropylbenzocycyclobutenol(1563118-44-4)

Safety Data

• Hazardous Substances Data: 1563118-44-4(Hazardous Substances Data)

Upstream product

• 3469-06-5 benzocyclobutenone 
• 23719-80-4 cyclopropylmagnesium bromide 

Downstream Products

• 14113-94-1 2-phenyl-1-cyclopropylethan-1-one 
• 39615-34-4 (2-methyl)phenyl cyclopropyl ketone 

Relevant articles and documents

RhI-catalyzed benzo/[7+1] cycloaddition of cyclopropyl-benzocyclobutenes and CO by merging thermal and metal-catalyzed C-C bond cleavages

A Rh-catalyzed benzo/[7+1] cycloaddition of cyclopropyl-benzocyclobutenes (CP-BCBs) and CO to benzocyclooctenones has been developed. In this reaction, CP-BCB acts as a benzo/7-C synthon and the reaction involves two C-C bond cleavages: a thermal electrocyclic ring-opening of the four-membered ring in CP-BCB and a Rh-catalyzed C-C cleavage of the cyclopropane ring.