156423-17-5

Basic information

• Product Name: (Z)-1-(2-iodovinyl)-2-methoxybenzene
• Synonyms: (Z)-1-(2-iodovinyl)-2-methoxybenzene
• CAS NO: 156423-17-5
• Molecular Weight: 260.074
• Mol File: 156423-17-5.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: (Z)-1-(2-iodovinyl)-2-methoxybenzene(CAS DataBase Reference)
• NIST Chemistry Reference: (Z)-1-(2-iodovinyl)-2-methoxybenzene(156423-17-5)
• EPA Substance Registry System: (Z)-1-(2-iodovinyl)-2-methoxybenzene(156423-17-5)

Safety Data

• Hazardous Substances Data: 156423-17-5(Hazardous Substances Data)

Upstream product

• 3020-28-8 (iodomethyl)triphenylphosphonium iodide 
• 135-02-4 ortho-anisaldehyde 
• 14737-91-8 (Z)-o-methoxycinnamic acid 

Downstream Products

• 767-91-9 1-ethynyl-2-methoxybenzene 
• 57103-24-9 (Z)-3-(2-methoxyphenyl)propenenitrile 

Relevant articles and documents

Cyclic Vinyl(aryl)iodonium Salts: Synthesis and Reactivity

A convenient, highly regioselective synthesis of five-membered cyclic vinyl(aryl)iodonium salts directly from β-iodostyrenes is presented. An X-ray crystal structure confirms the identity of these heterocycles. These λ3-iodanes can be converted

Oxidative Halo-Decarboxylation of α,β-Unsaturated Carboxylic Acids

A procedure for oxidative halo-decarboxylation of α,β-unsaturated carboxylic acids using iodosylbenzene, or iodosylbenzene diacetate, and N-chloro-, N-bromo-, or N-iodosuccinimide is presented.Good yields of the corresponding bromoalkenes are obtained when the α,β-unsaturated carboxylic acids are substituted with an aromatic substituent in the β-position and N-bromosuccinimide is used as the halogenation reagent.The scope of mainly the oxidative bromo-decarboxylation reaction is presented, and a tentative mechanism is proposed.