1564313-98-9Relevant academic research and scientific papers
Ambient synthesis of dienals via triazole-gold and amine catalysis relay
Motika, Stephen E.,Wang, Qiaoyi,Ye, Xiaohan,Shi, Xiaodong
, p. 290 - 293 (2015)
A highly efficient synthesis of substituted conjugated dienals was developed through a triazole-gold (TA-Au)-catalyzed propargyl vinyl ether rearrangement followed by an amine catalyzed allene-aldehyde tautomerization. Various substituted vinylogous aldehydes were prepared in one pot with good to excellent yields (up to 95%) under mild conditions with high atom economy.
