156470-13-2Relevant academic research and scientific papers
Synthesis and Transformations of some (Heteroaryl)acetylazides, (Heteroaryl)methyl Isocyanates and Alkyl (Heteroaryl)methyl Carbamates
Kocevar, Marijan
, p. 265 - 270 (2007/10/02)
The synthesis of two complex acetyl azides 6 and 10 having an heteroaryl residue bound to the acetyl group through the ring nitrogen, and their further transformations into the corresponding carbamates 7a-b and 11a-b and isocyanates 16 and 14 are described.Hydrolysis of these products results in the elimination of the substituted methyl group from the heterocyclic residue and formation of 1-unsubstituted heterocycles.A similar transformation was also observed under mass measurement conditions.
