156485-65-3Relevant academic research and scientific papers
Generation of silylethynolates via C-Si bond cleavage of disilylketenes induced by t-BuOK
Ito, Masato,Shirakawa, Eiji,Takaya, Hidemasa
, p. 1329 - 1331 (2002)
Disilylketenes undergo selective mono-desilylation upon treatment of t-BuOK in the presence of HMPA. The resulting silylethynolates are convertible to other disilylketenes in good yields. The intermediary silylethynolate was analyzed by NMR and IR spectroscopy.
