156543-41-8Relevant articles and documents
Synthesis and Prototropic Tautomerism of 1-n-Alkyl-3-methyl-4-nitroso-5-pyrazolones
Bartulin, J.,Belmar, J.,Gallardo, H.,Leon G.
, p. 561 - 564 (2007/10/02)
Nitrosation at C-4 of 1-n-alkyl-3-methyl-5-pyrazolones is achieved in about 50percent yield with sodium nitrite in hydrochloric acid medium.A tautomeric equilibrium in solution with a proton moving from the OH at C-5 to N-2 in the nitrosated pyrazolones is proposed.