156571-23-2Relevant academic research and scientific papers
Stable simple enols. Self-catalyzed E/Z-isomerization of the sterically crowded 2-(m-methoxymesityl)-1,2-dimesitylethenol
Rochlin, Elimelech,Rappoport, Zvi
, p. 1715 - 1720 (2007/10/03)
(E)-2-(m-Methoxymesityl)-1,2-dimesitylethenol (3a) isomerizes in the absence of a catalyst in solution to a 1.0:0.9 E/Z (3a/3b) equilibrium mixture. In CDCl3, the isomerization is first order in 3a within a run, but the plot of the rate constan
Mapping the Enantiomerization Routes of Triarylvinyl Propellers. Barriers for the Three-Ring Flip and the Three Different Two-Ring Flips of m-Methoxy-Substituted Trimesitylvinyl Isopropyl Ethers
Rochlin, Elimelech,Rappoport, Zvi
, p. 3857 - 3870 (2007/10/02)
E- and Z-(m-methoxymesityl)-1,2-dimesitylethenols (3a and 4a), their isopropyl ethers 3c and 4c, and 1-(m-methoxymesityl)-2,2-dimesitylvinyl isopropyl ether (2c) were prepared.X-ray structures of 3a and 3c were determinated.The rotational barriers for the
