156603-39-3

Basic information

• Product Name: 2-(bromomethyl)-3-tosyl-4-(trimethylsilyl)-1-butene
• Synonyms: 2-(bromomethyl)-3-tosyl-4-(trimethylsilyl)-1-butene
• CAS NO: 156603-39-3
• Molecular Weight: 375.402
• Mol File: 156603-39-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 2-(bromomethyl)-3-tosyl-4-(trimethylsilyl)-1-butene(CAS DataBase Reference)
• NIST Chemistry Reference: 2-(bromomethyl)-3-tosyl-4-(trimethylsilyl)-1-butene(156603-39-3)
• EPA Substance Registry System: 2-(bromomethyl)-3-tosyl-4-(trimethylsilyl)-1-butene(156603-39-3)

Safety Data

• Hazardous Substances Data: 156603-39-3(Hazardous Substances Data)

Upstream product

• 143100-97-4 1-((2-(chloromethyl)allyl)sulfonyl)-4-methylbenzene 
• 156603-26-8 3-(chloromethyl)-2-tosyl-1-(trimethylsilyl)-3-butene 

Downstream Products

• 23691-13-6 2-(bromomethyl)buta-1,3-diene 

Relevant articles and documents

A General Method for the Synthesis of 2-Alkyl Substituted 1,3-Dienes Starting from 2-(Chloromethyl)-3-tosylpropene

The alkylation of the monolithium derivative 5 of 2-(chloromethyl)-3-tosylpropene (1) with bromo- or iodo-methyltrimethylsilane affords the β-silyl sulfone 7, which after nucleophilic substitution of the chlorine atom followed by β-elimination of tosyltrimethylsilane, promoted by tetrabutylammonium fluoride (TBAF), gives 2-substituted conjugated dienes 6 and the outer-ring diene 14.Racemic ipsenol (10b), an aggregation pheromone of the bark beetle Ips paraconfusus Lanier, is prepared.