156631-02-6

Basic information

• Product Name: Methyl 1-allyl-4-oxocyclohexanecarboxylate
• Synonyms: Methyl 1-allyl-4-oxocyclohexanecarboxylate
• CAS NO: 156631-02-6
• Molecular Formula: C11H16O3
• Molecular Weight: 196.24294
• Mol File: 156631-02-6.mol
• Article Data: 1

Chemical Properties

• Appearance: /
• CAS DataBase Reference: Methyl 1-allyl-4-oxocyclohexanecarboxylate(CAS DataBase Reference)
• NIST Chemistry Reference: Methyl 1-allyl-4-oxocyclohexanecarboxylate(156631-02-6)
• EPA Substance Registry System: Methyl 1-allyl-4-oxocyclohexanecarboxylate(156631-02-6)

Safety Data

• Hazardous Substances Data: 156631-02-6(Hazardous Substances Data)

Upstream product

• 61692-29-3 methyl 4-trimethylsilyloxy-3-cyclohexenylcarboxylate 

Relevant articles and documents

A new asymmetric bridging annulation reaction involving the intramolecular Michael addition of chiral imines to enoates

Thermal cyclization of imine 12b led, after hydrolytic work-up, to bicyclic derivative 13b with a very high control of the three newly created stereogenic centers. In contrast adducts 13a and 13c, resulting from the cyclization of imines 12a and 12c respectively, were obtained as complex mixtures of stereomers.