1566556-29-3Relevant articles and documents
NHC-Cu-catalyzed addition of propargylboron reagents to phosphinoylimines. Enantioselective synthesis of trimethylsilyl-substituted homoallenylamides and application to the synthesis of S-(-)-cyclooroidin
Mszar, Nicholas W.,Haeffner, Fredrik,Hoveyda, Amir H.
supporting information, p. 3362 - 3365 (2014/03/21)
A catalytic method for the efficient and enantioselective addition of a 1-trimethylsilyl-substituted allene moiety to phosphinoylimines is presented. Transformations are promoted by 5.0 mol % of a copper complex of an N-heterocyclic carbene in the presenc