156666-06-7

Basic information

• Product Name: 2-(tri-n-butylstannyl)-2-cyclohexen-1-one
• Synonyms: 2-(tri-n-butylstannyl)-2-cyclohexen-1-one
• CAS NO: 156666-06-7
• Molecular Weight: 385.177
• Mol File: 156666-06-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 2-(tri-n-butylstannyl)-2-cyclohexen-1-one(CAS DataBase Reference)
• NIST Chemistry Reference: 2-(tri-n-butylstannyl)-2-cyclohexen-1-one(156666-06-7)
• EPA Substance Registry System: 2-(tri-n-butylstannyl)-2-cyclohexen-1-one(156666-06-7)

Safety Data

• Hazardous Substances Data: 156666-06-7(Hazardous Substances Data)

Upstream product

• 100073-20-9 tri-n-butyl-(1-cyclohex-1-enyl)-stannane 

Downstream Products

• 1421739-41-4 C₁₀H₁₃NO₄ 
• 15128-52-6 1,2,3,9-tetrahydro-4H-carbazol-4-one 
• 153865-32-8 1,2,3,9-tetrahydro-8-methyl-4H-carbazol-4-one 
• 608537-27-5 2-(5-bromo-2-nitrophenyl)-2-cyclohexen-1-one 
• 443303-80-8 2-(6-methoxycarbonyl-2-nitrophenyl)-2-cyclohexen-1-one 
• 198141-12-7 6,7,8,9-tetrahydro-5H-pyrido[3,2-b]indol-9-one 
• 443303-83-1 2-(3-methyl-2-nitrophenyl)-2-cyclohexen-1-one 
• 443303-81-9 4'-methoxy-2′-nitro-4,5-dihydro-[1,1'-biphenyl]-2(3H)-one 
• 176042-31-2 2′-nitro-4,5-dihydro-[1,1′-biphenyl]-2(3H)-one 

Relevant articles and documents

Regio- and Diastereoselective Synthesis of Stannyl Epoxy Alcohols by Direct Hydroxy Epoxidation of Vinylstannanes

The direct synthesis of stannyl epoxy alcohols 3 from vinylstannanes 1 is described.The procedure involves the photooxygenation of vinylstannanes 1, which proceeds in a highly regioselective manner with predominant hydrogen abstraction geminal to the stannyl group.Subsequent reaction of the resulting hydroperoxides 2 with Ti(OiPr)4 afforded in a one-pot procedure the epoxy alcohols 3 in high diastereomeric excess, which ranged from 81:19 to greater than 95:5.This convenient and effective method was applied to acyclic and cyclic vinylstannanes as well as to γ-hydroxyvinylstannane 1e, which was converted into the stannyl epoxy diol 3e.In this novel hydroxy epoxidation of vinylstannanes the regioselectivity of the singlet oxygen ene reaction (Schenck reaction) is controlled by the stannyl group. - Key Words: Vinylstannanes / Photooxygenation / Schenck reaction / Hydroxy epoxydation / Stannyl epoxy alcohols