156733-59-4Relevant articles and documents
Three donor-acceptor polymeric electrochromic materials employing 2,3-bis(4-(decyloxy)phenyl)pyrido[4,3-b]pyrazine as acceptor unit and thiophene derivatives as donor units
Zhao, Hui,Wei, Yuanyuan,Zhao, Jinsheng,Wang, Min
, p. 231 - 241 (2014)
In this study, 5,8-dibromo-2,3-bis(4-(decyloxy) phenyl) pyrido[4,3-b]pyrazine was synthesized and used as the acceptor unit, which then be coupled with three thiophene derivatives (3-methylthiophen, 3-methoxythiophen and 3,4-dimethoxythiophen) to give ris
Discotic nickel bis(dithiolene) complexes - Synthesis, optoelectrochemical and mesomorphic properties
Bui, Thanh-Tuan,Thiebaut, Olivier,Grelet, Eric,Achard, Marie-France,Garreau-De Bonneval, Benedicte,Moineau-Chane Ching, Kathleen I.
experimental part, p. 2663 - 2676 (2011/08/02)
Fifteen neutral long-chain-substituted discotic nickel bis(1,2-diphenyl-1, 2-ethenedithiolene) complexes [Ni(dpedt)2], including thirteen new compounds, have been synthesized by new short and efficient synthetic pathways. Physical investigations show that these complexes are thermally stable, possess good electron-accepting properties, and absorb light strongly in the near-infrared spectral region. Electrochemical and optical properties of [Ni(dpedt)2] depend moderately on the functionalities attached to the phenyl rings of the complexes. Their LUMO and HOMO energy levels are in the range -4.7 to -5.0 and -5.7 to -6.0 eV, respectively. Two octa(n-alkoxy)- substituted complexes exhibit a columnar liquid crystalline phase with hexagonal symmetry. These highly soluble complexes are potential candidates for use as electron-accepting and electron-transporting materials for active layers in organic electronic applications, such as field-effect transistors or photovoltaic devices. Electrochemical and optical studies as well as multiphase transition behavior are reported for a series of new nickel bis(dithiolene) complexes. The effects of the nature and position of the functional groupsattached to the periphery of the complexes are investigated. X-ray diffraction measurements regarding the hexagonal columnar mesophase are reported. Copyright
Discotic liquid crystals of transition metal complexes, 31: Establishment of mesomorphism and thermochromism of bis[1,2-bis(4-n-alkoxyphenyl)ethane-1,2-dithiolene]nickel complexes
Horie,Takagi,Hasebe,Ozawa,Ohta
, p. 1063 - 1071 (2007/10/03)
Two series of bis[1,2-bis(4-n-alkylphenyl)ethane-1,2-dithiolene]nickel, Cn-Ni (n= 1-12), and bis[1,2-bis(4-n-alkoxyphenyl)ethane-1,2-dithiolene]nickel, CnO-Ni(n = 1-12, 14, 16, 18), have been synthesized. Their mesomorphism, thermochromism, supramolecular structures and π-acceptor property have been investigated by using different scanning calorimetry, polarizing microscopy, temperature-dependent X-ray diffraction technique, electronic spectroscopy and cyclic voltammetry. From the X-ray diffraction and electronic spectral results, it was established that the CnO-Ni complexes for n ≤ 10 exhibit two differently colored discotic lamellar (DL) mesophases whereas none of the Cn-Ni complexes has a mesophase, and that the thermochromism (brown→green) is attributable to a slow transformation from the Ni-Ni bonded dimers to the Ni-S bonded dimers.