1567382-95-9Relevant academic research and scientific papers
Nickel-catalyzed decarboxylative arylation of heteroarenes through sp2 C-H functionalization
Yang, Ke,Wang, Peng,Zhang, Cheng,Kadi, Adnan A.,Fun, Hoong-Kun,Zhang, Yan,Lu, Hongjian
, p. 7586 - 7589 (2014)
The direct decarboxylative arylation of hetereoarenes with benzoic acids through a nickel-catalyzed sp2 C-H functionalization process was developed. This process provides the first examples of decarboxylative cross-coupling reactions with aroma
Photocatalytic hydrodefluorination: Facile access to partially fluorinated aromatics
Senaweera, Sameera M.,Singh, Anuradha,Weaver, Jimmie D.
, p. 3002 - 3005 (2014/03/21)
Polyfluorinated aromatics are essential to materials science as well as the pharmaceutical and agrochemical industries and yet are often difficult to access. This Communication describes a photocatalytic hydrodefluorination approach which begins with easily accessible perfluoroarenes and selectively reduces the C-F bonds. The method allows facile access to a number of partially fluorinated arenes and takes place with unprecedented catalytic activity using a safe and inexpensive amine as the reductant.
