156832-71-2Relevant academic research and scientific papers
A Pentamethylcyclopentadienyl Ligand Functionalized with a Pendant Pyridyl Group; Crystal Structure of its Ferrocene-Type Iron Complex
Siemeling, Ulrich,Neumann, Beate,Stammler, Hans-Georg
, p. 683 - 686 (2007/10/02)
The novel cyclopentadiene HMe4C5CH2CMe2py 2H has been prepared from tetramethylfulvene and lithiated 2-isopropyl-4-tert-butylpyridine.Lithiation of 2H with n-BuLi and subsequent reaction with FeCl2 yields the ferrocene (2)2Fe, which crystallizes in the triclinic space group P with a = 8.368(1), b = 8.468(1), c = 14.313(1) Angstroem, α = 80.64(1), β = 86.67(1), γ = 80.12(1) deg and V = 985.4(2) Angstroem3. - Keywords: Hemilabile Cyclopentadienyl Ligands, Pyridyl-Functionalized Cyclopentadienes, Pyridyl-Functionalized Ferrocene, Crystal Structure
