1569090-61-4

Basic information

• Product Name: 3,4-diallyl-2-m-tolylquinoline
• Synonyms: 3,4-diallyl-2-m-tolylquinoline
• CAS NO: 1569090-61-4
• Molecular Weight: 299.415
• Mol File: 1569090-61-4.mol

Chemical Properties

• CAS DataBase Reference: 3,4-diallyl-2-m-tolylquinoline(CAS DataBase Reference)
• NIST Chemistry Reference: 3,4-diallyl-2-m-tolylquinoline(1569090-61-4)
• EPA Substance Registry System: 3,4-diallyl-2-m-tolylquinoline(1569090-61-4)

Safety Data

• Hazardous Substances Data: 1569090-61-4(Hazardous Substances Data)

Upstream product

• 35466-83-2 allyl methyl carbonate 
• 1569090-64-7 1-azido-2-(3-m-tolylprop-2-yn-1-yl)benzene 

Relevant articles and documents

Efficient approach to allylated quinolines via palladium-catalyzed cyclization-allylation of 1-azido-2-(2-propynyl) benzenes with allyl methyl carbonate

The palladium-catalyzed cyclization-allylation reaction of ortho-azido propynylbenzenes 1 and allyl methyl carbonate 2d gives the corresponding allylated quinolines in moderate to good yields. The reaction of 1-azido-2-(2-propynyl)benzene 1a proceeds smoo

Synthesis of allylated quinolines/isoquinolines via palladium-catalyzed cyclization-allylation of azides and allyl methyl carbonate

A novel and efficient strategy for one-step synthesis of allylated quinolines and isoquinolines via palladium-catalyzed cyclization-allylation of azides and allyl methyl carbonate is developed for the first time. The results indicated that the regioselective synthesis of allyl- and diallyl-substituted quinolines/isoquinolines depends on different substituted groups at R1 and R4 positions, such as H or other groups. The reactions proceed smoothly in the presence of Pd(PPh3)4 and K3PO4 or NaOAc in DMF at 100°C to give the corresponding allyl- and diallyl-substituted quinolines and isoquinolines in good to high yields.