1569090-80-7

Basic information

• Product Name: C₁₂H₁₁N₃O
• Synonyms: C₁₂H₁₁N₃O
• CAS NO: 1569090-80-7
• Molecular Weight: 213.239
• Mol File: 1569090-80-7.mol

Chemical Properties

• CAS DataBase Reference: C₁₂H₁₁N₃O(CAS DataBase Reference)
• NIST Chemistry Reference: C₁₂H₁₁N₃O(1569090-80-7)
• EPA Substance Registry System: C₁₂H₁₁N₃O(1569090-80-7)

Safety Data

• Hazardous Substances Data: 1569090-80-7(Hazardous Substances Data)

Upstream product

• 54-96-6 3,4-diaminopyridine 
• 90-02-8 salicylaldehyde 

Downstream Products

• 1569090-81-8 C₁₉H₁₄BrN₃O₂ 
• 756492-97-4 N,N'-bis(2-hydroxybenzylidene)-3,4-pyridinediamine 

Relevant articles and documents

Synthesis, characterization, and thermodynamics of some new unsymmetrical Schiff bases of salicylaldehyde with 3,4-diaminopyridine and their cobalt(III) complexes

Some new Schiff bases derived from 3,4-diaminopyridine (3,4-DAP) and their new unsymmetrical Co(III) five coordinate complexes described as [Co(Chel)(L)]ClO4×H2O where (Chel) is the deprotonated form of a series of unsymmetric ligands containing 3,4-diaminopyridine (3,4-DAP) and substituted salicylaldehyde moieties and a new Co(III) six coordinate Co(III) complex, were synthesized and characterized by 1H NMR, IR, UV-Vis, and elemental analysis. For the new synthesized five coordinate complexes, the formation constants of the interaction of the Co(III) Schiff bases with various donors were measured spectrophotometrically. The trend of the formation constants of the five coordinate Co(III) Schiff base complexes toward a given phosphine is as follow: 5-H > 5-Br and the formation constants trend of these donors are as follow: PBu3 > PPh 2Me. Furthermore the adduct formation of the five coordinate [Co(3,4-Salpyr)(PBu3)] ClO4×H2O, with aromatic amines shows the following binding trend: Im > 2-MeIm > 2-EtIm > BzIm. The trend of the formation constants of Co(III) Schiff base complexes toward a given donor according to the phosphine axial ligand is as follow: PBu3 > PPh2Me.