156927-62-7

Basic information

• Product Name: Carbamic acid, (1-methyl-2-butenyl)-, 1,1-dimethylethyl ester, (E)-(-)- (9CI)
• Synonyms: Carbamic acid, [(1S,2E)-1-methyl-2-butenyl]-, 1,1-dimethylethyl ester (9CI)
• CAS NO: 156927-62-7
• Molecular Formula: C10H19NO2
• Molecular Weight: 185.26
• Product Categories: N-BOC
• Mol File: 156927-62-7.mol
• Article Data: 3

Chemical Properties

• Appearance: /
• CAS DataBase Reference: Carbamic acid, (1-methyl-2-butenyl)-, 1,1-dimethylethyl ester, (E)-(-)- (9CI)(CAS DataBase Reference)
• NIST Chemistry Reference: Carbamic acid, (1-methyl-2-butenyl)-, 1,1-dimethylethyl ester, (E)-(-)- (9CI)(156927-62-7)
• EPA Substance Registry System: Carbamic acid, (1-methyl-2-butenyl)-, 1,1-dimethylethyl ester, (E)-(-)- (9CI)(156927-62-7)

Safety Data

• Hazardous Substances Data: 156927-62-7(Hazardous Substances Data)

Upstream product

• 887615-52-3 (R)-N-tert-butoxycarbonyl-N-[(E)-1-methyl-2-butenyl]hexylsulfenamide 
• 1530-32-1 ethyltriphenylphosphonium bromide 
• 79069-50-4 Boc-Ala-H 
• 1754-88-7 ethylenetriphenylphosphorane 

Relevant articles and documents

Oxaziridine-mediated amination of branched allylic sulfides: Stereospecific formation of allylic amine derivatives via [2,3]-sigmatropic rearrangement

Reaction of branched allylic sulfides with the N-Bocoxaziridine 1 results in [2,3]-sigmatropic rearrangement of the intermediate allylic N-Boc-surfimides with a high level of chirality transfer. The first example of formation of a quaternary stereocenter

Allylsilanes derived from aminoacids in the synthesis of piperidine and pyrrolidins derivatives

Allylsilanes preapared from α-aminoacids react with acyl chlorides in the presence of TiCl4 to give unsaturated amino ketones, easily transformed into pyrrolidine derivatives, whereas addition to aldehydes gave 2,6-disubstituted tetrahydropyrid