1569524-37-3

Basic information

• Product Name: trifluoro(3-methoxybenzyl)-λ⁴-borane potassium salt
• Synonyms: trifluoro(3-methoxybenzyl)-λ⁴-borane potassium salt
• CAS NO: 1569524-37-3
• Molecular Weight: 228.063
• Mol File: 1569524-37-3.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: trifluoro(3-methoxybenzyl)-λ⁴-borane potassium salt(CAS DataBase Reference)
• NIST Chemistry Reference: trifluoro(3-methoxybenzyl)-λ⁴-borane potassium salt(1569524-37-3)
• EPA Substance Registry System: trifluoro(3-methoxybenzyl)-λ⁴-borane potassium salt(1569524-37-3)

Safety Data

• Hazardous Substances Data: 1569524-37-3(Hazardous Substances Data)

Usage

General Description

Trifluoro(3-methoxybenzyl)-λ⁴-borane potassium salt is a chemical compound that consists of a trifluoromethyl substituent attached to a boron atom which is coordinated with a 3-methoxybenzyl ligand and a potassium cation. This salt is commonly used as a reagent in organic synthesis for the formation of carbon-carbon and carbon-heteroatom bonds. It is known for its high reactivity and selectivity in various chemical reactions, particularly in the preparation of arylboronic acids and their derivatives. Trifluoro(3-methoxybenzyl)-λ⁴-borane potassium salt is a versatile and important intermediate in the field of organoboron chemistry, making it a valuable tool for synthetic chemists working on the development of new pharmaceuticals, agrochemicals, and materials.

Upstream product

• 6971-51-3 3-methoxybenzyl alcohol 
• 797762-23-3 2-(3-methoxybenzyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane 
• 824-98-6 m-methoxybenzyl chloride 
• 874-98-6 1-bromomethyl-3-methoxybenzene 
• 73183-34-3 bis(pinacol)diborane 

Downstream Products

• 191085-63-9 N-(3-methoxybenzyl)-4-methylbenzenesulfonamide 
• 1569438-20-5 (Z)-5-(3-chloro-4-methoxybenzylidene)-4-isopropyl-3-(3-methoxybenzyl)furan-2(5H)-one 

Relevant articles and documents

Extremely facile formation of the pavine alkaloid skeleton by the photoreaction between isoquinoline and benzyltrifluoroborate

Appling the photo-benzylation of isoquinoline with benzyltrifluoroborate, an extremely facile method for the construction of a pavine alkaloid skeleton was developed. When 3-methoxybenzylboron reagents were employed to the reaction, it was found that not

Dual Nickel- and Photoredox-Catalyzed Enantioselective Desymmetrization of Cyclic meso-Anhydrides

The enantioselective desymmetrization of cyclic meso-anhydrides with benzyl trifluoroborates under nickel-photoredox catalysis is described. The reaction tolerates a variety of sterically and electronically different trifluoroborates, as well as structurally unique cyclic anhydrides. The trans isomer of the keto-acid products is also observed at varying levels dependent on the trifluoroborate identity and relative catalyst loading. A mechanism involving decarbonylation and Ni?C bond homolysis of a NiII adduct is proposed. This feature allows access to a trans keto-acid as the major product in high enantioselectivity from a cis meso anhydride.