156975-36-9Relevant academic research and scientific papers
Synthesis, molecular structure, and reactivity of a half-sandwich vanadium(III) imido complex: The first vanadium (V) alkylidene
Buijink, Jan-Karel F.,Teuben, Jan H.,Kooijman, Huub,Spek, Anthony L.
, p. 2922 - 2924 (2008/10/08)
One of the trimethylphosphine ligands in CpV(NAr)(PMe3)2 (3; Ar = 2,6-C6H3-i-Pr2), obtained by magnesium reduction of CpV(NAr)Cl2 (2), can be substituted by CO, ethylene, or diphenylacetylene to give the corresponding π-acceptor (L) complex CpV(NAr)(L)-(PMe3) (L = CO, 4; L = C2H4, 5; L = PhC≡Ph, 6). 3 reacts with Ph3P=CHPh to form the first vanadium(V) alkylidene, CpV(NAr)(=CHPh)(PMe3) (7).
