157024-27-6Relevant articles and documents
A Novel Intramolecular Silyl Nitronate Cycloaddition Route to Dihydrofuraldehydes and Dihydropyranaldehydes
Duffy, Jetty L.,Kurth, Mark J.
, p. 3783 - 3785 (1994)
The novel transformation (1 -> 3) of propargylic or homopropargylic nitroethers to dihydrofuraldehydes (n=0) or dihydropyranaldehydes (n=1) is reported.The transformation proceeds by a silyl nitronate olefin cycloaddition to an N-isox
Preparation of 7-substituted 4,5-dihydro-7H-pyrano[3,4-c]-isoxazole derivatives
Yamada, Koji,Yamada, Fumio,Somei, Masanori
, p. 685 - 690 (2007/10/03)
An easy approach to 7-substituted 4,5-dihydro-7H-pyrano[3,4-c]-isoxazole derivatives (3a-b and 6a-d) is described by the reaction of 2-aryl substituted 1-nitro-3-oxa-6-heptynes (2, 5a and 5b) with n-BuLi, followed by treatment with acetic anhydride.
A facile synthesis of 3,4-disubstituted isoxazole derivatives by regioselective cleavage of pyrano[3,4-c]isoxazoles with boron trihalide
Kim, Hyung Jin,Lee, Young Ju
, p. 3527 - 3537 (2007/10/03)
4,5-Dihydro-7H-pyrano[3,4-c]isoxazoles 4 were efficiently prepared by the intramolecular nitrile oxide-alkyne cycloaddition following the Michael addition of sodium alkoxide to nitroalkene. Reaction of pyrano[3,4- c]isoxazole 4 with boron trihalide result