1570510-99-4

Basic information

• Product Name: (R)-2-(1-(benzofuran-5-yl)-3-phenylpropyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane
• CAS NO: 1570510-99-4
• Molecular Weight: 362.277
• Mol File: 1570510-99-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (R)-2-(1-(benzofuran-5-yl)-3-phenylpropyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane(CAS DataBase Reference)
• NIST Chemistry Reference: (R)-2-(1-(benzofuran-5-yl)-3-phenylpropyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane(1570510-99-4)
• EPA Substance Registry System: (R)-2-(1-(benzofuran-5-yl)-3-phenylpropyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane(1570510-99-4)

Safety Data

• Hazardous Substances Data: 1570510-99-4(Hazardous Substances Data)

Upstream product

• 134414-86-1 (3,3-dibromopropyl)benzene 
• 73183-34-3 bis(pinacol)diborane 
• 23145-07-5 5-bromobenzofuran 
• 1379610-52-2 4,4,5,5‐tetramethyl‐2‐[5‐phenyl‐1‐(4,4,5,5‐tetramethyl‐1,3,2‐dioxaborolan‐2‐yl)propyl]‐1,3,2‐dioxaborolane 

Relevant articles and documents

A catalytic enantiotopic-group-selective Suzuki reaction for the construction of chiral organoboronates

Catalytic enantiotopic-group-selective cross-couplings of achiral geminal bis(pinacolboronates) provide a route for the construction of nonracemic chiral organoboronates. In the presence of a chiral monodentate taddol-derived phosphoramidite ligand, these reactions occur with high levels of asymmetric induction. Mechanistic experiments with chiral 10B-enriched geminal bis(boronates) suggest that the reaction occurs by a stereochemistry-determining transmetalation that occurs with inversion of configuration at carbon.