1570511-03-3

Basic information

• Product Name: (R)-2-(cyclohexyl(4-methoxyphenyl)methyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane
• CAS NO: 1570511-03-3
• Molecular Weight: 330.275
• Mol File: 1570511-03-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (R)-2-(cyclohexyl(4-methoxyphenyl)methyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane(CAS DataBase Reference)
• NIST Chemistry Reference: (R)-2-(cyclohexyl(4-methoxyphenyl)methyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane(1570511-03-3)
• EPA Substance Registry System: (R)-2-(cyclohexyl(4-methoxyphenyl)methyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane(1570511-03-3)

Safety Data

• Hazardous Substances Data: 1570511-03-3(Hazardous Substances Data)

Upstream product

• 696-62-8 para-iodoanisole 
• 1512864-19-5 2,2'-(cyclohexylmethylene)bis(4,4,5,5-tetramethyl-1,3,2-dioxaborolane) 

Relevant articles and documents

A catalytic enantiotopic-group-selective Suzuki reaction for the construction of chiral organoboronates

Catalytic enantiotopic-group-selective cross-couplings of achiral geminal bis(pinacolboronates) provide a route for the construction of nonracemic chiral organoboronates. In the presence of a chiral monodentate taddol-derived phosphoramidite ligand, these reactions occur with high levels of asymmetric induction. Mechanistic experiments with chiral 10B-enriched geminal bis(boronates) suggest that the reaction occurs by a stereochemistry-determining transmetalation that occurs with inversion of configuration at carbon.