15706-69-1Relevant articles and documents
Pronounced solvent effect on the hydrostannylation of propargylic alcohol derivatives with nBu3SnH/Et3B at room temperature
Oderinde, Martins S.,Organ, Michael G.
supporting information, p. 2615 - 2618 (2013/03/14)
The solvent is key: A general protocol is described for the hydrostannylation of propargyl alcohol derivatives at room temperature using Et3B/O2 as the promoter (see scheme). Rate and mechanistic studies point to a different autoxidation product of Et3B in THF than is observed in benzene, the typical solvent. Copyright
