157085-57-9Relevant articles and documents
Synthesis of β-dimorphecolic acid exploiting highly stereoselective reduction of a side-chain carbonyl group in a π-allyltricarbonyliron lactone complex
Ley, Steven V.,Meek, Graham
, p. 1125 - 1133 (2007/10/03)
A highly enantioselective synthesis of β-dimorphecolic acid 1 is reported. The synthesis features a diastereoselective reduction of the ketone 4, in which the tricarbonyliron lactone tether induces a 1,5 transfer of chirality, followed by a stereoselectiv