157105-48-1Relevant articles and documents
Enantioselective synthesis of tetrahydroisoquinolines and benzazepines by silane terminated heck reactions with the chiral ligands (+)-TMBTP and (R)-BITIANP
Tietze, Lutz F.,Thede, Kai,Schimpf, Ralph,Sannicolo, Franco
, p. 583 - 584 (2000)
The intramolecular Heck reaction of the iodoaryl compound 1 with a (Z)- allyl silane moiety in the presence of the chiral ligand (+)-TMBTP 13 leads to the benzazepine 5b with 92% ee, whereas 3 with an (E)-allyl silane moiety in the presence of the chiral