1571105-24-2Relevant articles and documents
Copper-catalyzed synthesis of 1,3-butadienylphosphine oxides and chemoselective phosphoryl reduction to stereodefined 1,3-butadienylphosphines
Gatignol, Jérémie,Alayrac, Carole,Lohier, Jean-Fran?ois,Ballester, Jorge,Taillefer, Marc,Gaumont, Annie-Claude
, p. 2822 - 2826 (2013)
Copper-catalyzed CP cross-coupling reactions between diphenylphosphine oxide and various 1-bromo-1,3-butadienes readily provided a set of functionalized 1,3-butadienyldiphenylphosphine oxides. Application of the latter to the synthesis of stereodefined 1,3-butadienyldiphenylphosphines was successfully achieved via chemoselective reduction of their phosphoryl moiety.