1571900-38-3Relevant academic research and scientific papers
Palladium-Catalyzed Addition/Cyclization of (2-Hydroxyaryl)boronic Acids with Alkynylphosphonates: Access to Phosphacoumarins
Chen, Sirui,Gao, Yuxing,Hu, Shanshan,Ma, Dumei,Pan, Jiaoting,Tu, Song,Yin, Yingwu,Zhao, Yufen
supporting information, p. 8156 - 8160 (2020/11/02)
A facile palladium-catalyzed addition/cyclization of (2-hydroxyaryl)boronic acids with alkynylphosphonates has been developed, providing an effective strategy to construct a series of valuable phosphacoumarins. This methodology features excellent regioselectivity and broad substrate tolerance.
Gold-catalyzed hydroarylation of aryl alkynylphosphonates for the synthesis of phosphacoumarins
Kim, Cheol-Eui,Ryu, Taekyu,Kim, Sanghyuck,Lee, Kooyeon,Lee, Chang-Hee,Lee, Phil Ho
, p. 2873 - 2883 (2014/03/21)
Intramolecular hydroarylation using aryl alkynylphosphonates proceeds smoothly with a gold/ silver catalyst in the presence of trifluoromethanesulfonic acid (TfOH) in the 6-endo mode, thus affording a unique synthetic method for phosphacoumarins having various functional groups, which could be a privileged structure and prevalent scaffold in phosphorus heterocycles.
