1571900-46-3Relevant academic research and scientific papers
Gold-catalyzed hydroarylation of aryl alkynylphosphonates for the synthesis of phosphacoumarins
Kim, Cheol-Eui,Ryu, Taekyu,Kim, Sanghyuck,Lee, Kooyeon,Lee, Chang-Hee,Lee, Phil Ho
, p. 2873 - 2883 (2014/03/21)
Intramolecular hydroarylation using aryl alkynylphosphonates proceeds smoothly with a gold/ silver catalyst in the presence of trifluoromethanesulfonic acid (TfOH) in the 6-endo mode, thus affording a unique synthetic method for phosphacoumarins having various functional groups, which could be a privileged structure and prevalent scaffold in phosphorus heterocycles.
