1572949-29-1Relevant articles and documents
Competition between sp3-C-N vs sp3-C-F reductive elimination from PdIV complexes
Pérez-Temprano, Mónica H.,Racowski, Joy M.,Kampf, Jeff W.,Sanford, Melanie S.
, p. 4097 - 4100 (2014)
This communication describes the design of a model system that allows direct investigation of competing sp3-C-N and sp3-C-F bond-forming reductive elimination from a PdIV fluoro sulfonamide complex. The reductive elimination selectivity varies dramatically as a function of reaction additives. A mechanism is proposed that provides a rationale for these effects.