15733-49-0Relevant academic research and scientific papers
Regioselective radical cyclization initiated by the reaction of allylic hydroperoxides with iron(II) sulfate
Masuyama, Araki,Sugawara, Tomohiro,Nojima, Masatomo,McCullough, Kevin J.
, p. 353 - 366 (2007/10/03)
Treatment of 1-methyl-2-methylene-1-cyclohexyl hydroperoxide with a mixture of FeSO4/CuCl2 yielded 1-(1-chlorocyclohexyl)ethanone as the major product consistent with 6-endo-trig cyclization of the intermediate 5-acetylhex-5-enyl rad
Regio- and stereoselectivity in the solvomercuriation and intramolecular alkoxymercuriation of cyclic unsaturated alcohols
Senda, Yasuhisa,Takayanagi, Satomi,Sudo, Tomomi,Itoh, Hiroki
, p. 270 - 278 (2007/10/03)
The regio- and stereoselectivity in the solvomercuriation and intramolecular alkoxymercuriation of several cyclic olefinic alcohols were examined. The regioselecuvity is controlled mainly by electronic factors, while the stereoselectivity is controlled by
Thermodynamics of o-Menthene Isomerization and Additivity of Entropies of Alicyclic Hydrocarbons
Roganov, G. N.,Kabo, G. Ya.,Stolyarova, L. G.
, p. 1408 - 1411 (2007/10/02)
Equilibrium of the isomerization reactions of five o-menthenes is studied and the values of their thermodynamic characteristics are calculated.The stabilizing intramolecular interaction in trans-8-menthene is assessed qualitatively.An additive scheme for calculating the entropy characteristics of alicyclic hydrocarbons and their reactions with regard for participation of effective atoms in formation of cyclic systems, molecular symmetry, and entropy of mixing of the enantiomeric forms is suggested.
