157430-14-3Relevant articles and documents
Mitsunobu reactions of glycals with phenoxide nucleophiles are S(N)2'-selective
Sobti,Sulikowski
, p. 3661 - 3664 (1994)
The C3-hydroxyl group of L-rhamnal (4) and D-glucal 7 underwent S(N)2'-selective Mitsunobu displacements with substituted phenoxide nucleophiles. These reactions provide access to the corresponding α-arylglycoside.
Reagent Controlled Direct Dehydrative Glycosylation with 2-Deoxy Sugars: Construction of the Saquayamycin Z Pentasaccharide
Mizia, J. Colin,Bennett, Clay S.
, p. 5922 - 5927 (2019/08/27)
The first synthesis of the pentasaccharide fragment of the angucycline antibiotic saquayamycin Z is described. By using our sulfonyl chloride mediated reagent controlled dehydrative glycosylation, we are able to assemble the glycosidic linkages with high