1574538-07-0

Basic information

• Product Name: (μ-1,13-bis{2-[4-(2,2′-bipyridin-5-yl)-1H-1,2,3-triazol-1-yl]phenyl}-1,4,7,10,13-pentaoxatridecane)tetrakis(phenylethynyl)diplatinum(II)
• CAS NO: 1574538-07-0
• Molecular Weight: 1583.54
• Mol File: 1574538-07-0.mol

Chemical Properties

• CAS DataBase Reference: (μ-1,13-bis{2-[4-(2,2′-bipyridin-5-yl)-1H-1,2,3-triazol-1-yl]phenyl}-1,4,7,10,13-pentaoxatridecane)tetrakis(phenylethynyl)diplatinum(II)(CAS DataBase Reference)
• NIST Chemistry Reference: (μ-1,13-bis{2-[4-(2,2′-bipyridin-5-yl)-1H-1,2,3-triazol-1-yl]phenyl}-1,4,7,10,13-pentaoxatridecane)tetrakis(phenylethynyl)diplatinum(II)(1574538-07-0)
• EPA Substance Registry System: (μ-1,13-bis{2-[4-(2,2′-bipyridin-5-yl)-1H-1,2,3-triazol-1-yl]phenyl}-1,4,7,10,13-pentaoxatridecane)tetrakis(phenylethynyl)diplatinum(II)(1574538-07-0)

Safety Data

• Hazardous Substances Data: 1574538-07-0(Hazardous Substances Data)

Upstream product

• 1309926-64-4 (5-ethynyl-2,2-bipyridine)bis(phenylethynyl)platinum(II) 
• 1574538-10-5 1,13-bis(2-azidophenyl)-1,4,7,10,13-pentaoxatridecane 

Relevant articles and documents

Tracking intramolecular interactions in flexibly linked binuclear Platinum(II) complexes

In this work we describe the synthesis and the photophysical and electrochemical characterization of binuclear PtII complexes. Using a modular click chemistry approach, we decorated different flexible bridging units with (bpy)PtII bisacetylides (bpy = 2,2′-bipyridine). Intramolecular excimer formation originating from PtII-Pt II and π-π interactions was investigated by steady-state and time-resolved emission spectroscopy in dilute solution. We observed that linkers bringing the metallic centers in close proximity favor both ground-state coupling and excimer formation. These interactions lead to changes in the photophysical and electrochemical properties, which can be tuned by the choice of solvent.