1574568-96-9Relevant academic research and scientific papers
Copper-catalyzed oxidative coupling of acids with alkanes involving dehydrogenation: Facile access to allylic esters and alkylalkenes
Wang, Cheng-Yong,Song, Ren-Jie,Wei, Wen-Ting,Fan, Jian-Hong,Li, Jin-Heng
, p. 2361 - 2363 (2015)
We here describe a new copper-catalyzed oxidative coupling of acids with alkanes for the selective synthesis of allylic esters and alkylalkenes. This method achieves multiple dehydrogenation and esterification, representing a new unactivated C(sp3/s
Allylic oxidation of alkenes catalyzed by a copper-aluminum mixed oxide
Garcia-Cabeza, Ana Leticia,Marin-Barrios, Ruben,Moreno-Dorado, F. Javier,Ortega, Maria J.,Massanet, Guillermo M.,Guerra, Francisco M.
supporting information, p. 1598 - 1601 (2014/04/17)
A strategy for the allylic oxidation of cyclic alkenes with a copper-aluminum mixed oxide as catalyst is presented. The reaction involves the treatment of an alkene with a carboxylic acid employing tert-butyl hydroperoxide as the oxidant. In all cases, the corresponding allylic esters are obtained. When l-proline is employed, the allylic alcohol or ketone is obtained. The oxidation of cyclohexene and valencene has been optimized by design of experiments (DoE) statistical methodology.
