157526-54-0

Basic information

• Product Name: [OsCl(SC₆F₅)2(SC₆H₄F)(P(CH₃)2(C₆H₅))]
• CAS NO: 157526-54-0
• Molecular Weight: 889.212
• Mol File: 157526-54-0.mol

Chemical Properties

• CAS DataBase Reference: [OsCl(SC₆F₅)2(SC₆H₄F)(P(CH₃)2(C₆H₅))](CAS DataBase Reference)
• NIST Chemistry Reference: [OsCl(SC₆F₅)2(SC₆H₄F)(P(CH₃)2(C₆H₅))](157526-54-0)
• EPA Substance Registry System: [OsCl(SC₆F₅)2(SC₆H₄F)(P(CH₃)2(C₆H₅))](157526-54-0)

Safety Data

• Hazardous Substances Data: 157526-54-0(Hazardous Substances Data)

Upstream product

• 135444-30-3 {Os(III)Cl(SC₆HF₄)3(PMe₂Ph)} 

Relevant articles and documents

Thiolate Complexes of Osmium(IV): Preparation of (R=C6F5, C6F4H-4, C6H4F-4 or Ph, R'=Ph; R=C6F5 or C6F4H-4, R'3=Me2Ph) and (X=F or CF3): Crystal Structures of and

The diamagnetic osmium(IV) complexes (R=C6F5, C6F4H-4, C6H4F-4, or Ph, R'=Ph; R=C6F5 or C6F4H-4, R'3=Me2Ph) and (X=F or CF3) have been prepared.The complex has an essentially trigonal-bipyramidal structure with an apical PPh3 group ap 2.414(5), mean Os-Seq, 2.207(7) Angstroem>.The structure of is a somewhat distorted triagonal bipyramid with apical Cl(1-) and PMe2Ph groups .The spectroscopic properties of these compounds are reported and the possibility of isomerism in solution is discussed.