157544-85-9

Basic information

• Product Name: (1R,2R,6R,7R)-9-<<(tert-butyl)dimethylsilyl>oxy>-4-phenyl-3,10-dioxa-5-azatricyclo<5.2.1.0^2,6>deca-4,8-diene
• Synonyms: (1R,2R,6R,7R)-9-<<(tert-butyl)dimethylsilyl>oxy>-4-phenyl-3,10-dioxa-5-azatricyclo<5.2.1.0^2,6>deca-4,8-diene
• CAS NO: 157544-85-9
• Molecular Weight: 343.498
• Mol File: 157544-85-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (1R,2R,6R,7R)-9-<<(tert-butyl)dimethylsilyl>oxy>-4-phenyl-3,10-dioxa-5-azatricyclo<5.2.1.0^2,6>deca-4,8-diene(CAS DataBase Reference)
• NIST Chemistry Reference: (1R,2R,6R,7R)-9-<<(tert-butyl)dimethylsilyl>oxy>-4-phenyl-3,10-dioxa-5-azatricyclo<5.2.1.0^2,6>deca-4,8-diene(157544-85-9)
• EPA Substance Registry System: (1R,2R,6R,7R)-9-<<(tert-butyl)dimethylsilyl>oxy>-4-phenyl-3,10-dioxa-5-azatricyclo<5.2.1.0^2,6>deca-4,8-diene(157544-85-9)

Safety Data

• Hazardous Substances Data: 157544-85-9(Hazardous Substances Data)

Upstream product

• 157506-26-8 (1R,2R,6R,7R,9S)-<9-exo-cyano-4-phenyl-3,10-dioxa-5-azatricyclo<5.2.1.0^2,6>dec-4-en-2-endo-yl(1S)-camphanate> 
• 88764-13-0 (1R,2R,4R)-2-exo-cyano-7-oxabicyclo<2.2.1>hept-5-en-2-endo-yl(1S)-camphanate 
• 77377-52-7 N-methyl-N-tert-butyldimethylsilyl-1,1,1-trifluoroacetamide 

Downstream Products

• 157506-31-5 methyl 3-amino-1,5-anhydro-2-O,3-N-benzoyl-3-deoxy-α-L-talofuranuronate 
• 157506-33-7 3-amino-1,5-anhydro-2-O,3-N-benzoyl-3-deoxy-α-L-talofuranose 

Relevant articles and documents

Total asymmetric synthesis of 3-amino-3-deoxy-L-talose and derivatives

(1R,2R,4R)-2-exo-Cyano-7-oxabicyclo[2.2.1]hept-5-en-2-yl (1S')-camphanate [(+)-1, Diels-Alder adduct of furan to 1-cyanovinyl (1S)-camphanate] was transformed with high stereoselectivity into (1R,2R,6R,7R)-4-phenyl-3,10-dioxa-5-azatricyclo[5.2.1.02,6