157555-90-3

Upstream product

• 6893-65-8 1,2-di-O-isopropylidene-5-O-tosyl-D-xylofuranose 
• 18162-48-6 tert-butyldimethylsilyl chloride 
• 92413-83-7 3-(O-tert-butyldimethylsilyl)-1,2-O-isopropylidene-5-O-(p-tolylsulfonyl)-α-D-xylofuranose 
• 108-98-5 thiophenol 

Downstream Products

• 124502-76-7 3-(O-tert-butyldimethylsilyl)-5-chloro-1,2-O-isopropylidene-5-S-phenyl-5-thio-α-D-xylofuranose 
• 124502-84-7 6,10-anhydro-3-O-(tert-butyldimethylsilyl)-8,9-dideoxy-1,2-O-isopropylidene-5-S-phenyl-5-thio-α-D-glycero-L-ido-decofuranos-7-ulose 
• 124502-84-7 (S)-2-{[(3aR,5S,6R,6aR)-6-(tert-Butyl-dimethyl-silanyloxy)-2,2-dimethyl-tetrahydro-furo[2,3-d][1,3]dioxol-5-yl]-phenylsulfanyl-methyl}-dihydro-pyran-3-one 

Relevant academic research and scientific papers

Chemistry of the Herbicidins. Reactivity of Silyl Enol Ethers Derived from Simple and Carbohydrate-based Tetrahydropyrans

Details are described of preliminary synthetic studies, based on Lewis acid-mediated alkylation of a silyl enol ether, that were directed towards the C11 glycoside of the herbicidin class of nucleosides.The chemistry presented focuses on limitations encou