157584-97-9Relevant academic research and scientific papers
Regioselective S -allylation of thiols with cyclic Baylis-Hillman acetates
Erray, Imen,Oble, Julie,Poli, Giovanni,Rezgui, Farhat
, p. 128 - 136 (2014/01/23)
An efficient and mild S-allylation of thiols with cyclic Baylis-Hillman acetates with no need of a transition-metal-catalyst or an expensive additive is described. Allyl sulfides are prepared in good to excellent yields (60-97%) and a single regioisomer was observed in all cases.
A General Synthesis of 2-Substituted Cyclohex-2-enones
Armitage, Mark A.,Lathbury, David C.,Mitchell, Michael B.
, p. 1551 - 1552 (2007/10/02)
A new synthesis of 2-substituted cyclohex-2-enones has been achieved using a sequence involving the aldol reaction of the aluminium enolate derived from thiolate addition to cyclohex-2-enone, followed by dehydration, rearrangement and desulfurisation.
