Cas 157620-25-2,C10H6(C6H4)(CSO)Ru(C5H5)(P(C6H5)2CH2P(C6H5)2)(1+)*BF4(1-)=[C10H6(C6H4)(CSO)Ru(C5H5)(P(C6H5)2CH2P(C6H5)2)]BF4

157620-25-2

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Basic information

Product Name: C₁₀H₆(C₆H₄)(CSO)Ru(C₅H₅)(P(C₆H₅)2CH₂P(C₆H₅)2)⁽¹⁺⁾*BF₄^(1-)=[C₁₀H₆(C₆H₄)(CSO)Ru(C₅H₅)(P(C₆H₅)2CH₂P(C₆H₅)2)]BF₄
Synonyms:
CAS NO:157620-25-2
Molecular Formula:
Molecular Weight: 899.698
EINECS: N/A
Product Categories: N/A

Chemical Properties

Melting Point: N/A
Boiling Point: N/A
Flash Point: N/A
Appearance: N/A
Density: N/A
Refractive Index: N/A
Storage Temp.: N/A
Solubility: N/A
CAS DataBase Reference: C₁₀H₆(C₆H₄)(CSO)Ru(C₅H₅)(P(C₆H₅)2CH₂P(C₆H₅)2)⁽¹⁺⁾*BF₄^(1-)=[C₁₀H₆(C₆H₄)(CSO)Ru(C₅H₅)(P(C₆H₅)2CH₂P(C₆H₅)2)]BF₄(CAS DataBase Reference)
NIST Chemistry Reference: C₁₀H₆(C₆H₄)(CSO)Ru(C₅H₅)(P(C₆H₅)2CH₂P(C₆H₅)2)⁽¹⁺⁾*BF₄^(1-)=[C₁₀H₆(C₆H₄)(CSO)Ru(C₅H₅)(P(C₆H₅)2CH₂P(C₆H₅)2)]BF₄(157620-25-2)
EPA Substance Registry System: C₁₀H₆(C₆H₄)(CSO)Ru(C₅H₅)(P(C₆H₅)2CH₂P(C₆H₅)2)⁽¹⁺⁾*BF₄^(1-)=[C₁₀H₆(C₆H₄)(CSO)Ru(C₅H₅)(P(C₆H₅)2CH₂P(C₆H₅)2)]BF₄(157620-25-2)

Safety Data

Hazard Codes: N/A
Statements: N/A
Safety Statements: N/A
WGK Germany:
RTECS:
HazardClass: N/A
PackingGroup: N/A
Hazardous Substances Data: 157620-25-2(Hazardous Substances Data)

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Check Digit Verification of cas no

The CAS Registry Mumber 157620-25-2 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 1,5,7,6,2 and 0 respectively; the second part has 2 digits, 2 and 5 respectively.
Calculate Digit Verification of CAS Registry Number 157620-25:
(8*1)+(7*5)+(6*7)+(5*6)+(4*2)+(3*0)+(2*2)+(1*5)=132
132 % 10 = 2
So 157620-25-2 is a valid CAS Registry Number.

157620-25-2Upstream product

157620-54-7 Ru(C₅H₅)(P(C₆H₅)2CH₂P(C₆H₅)2(SC₄H₄))⁽¹⁺⁾*BF₄^(1-)=[Ru(C₅H₅)(P(C₆H₅)2CH₂P(C₆H₅)2(SC₄H₄))]BF₄

157620-25-2Downstream Products

157620-25-2Relevant academic research and scientific papers

Synthesis and ring-opening reactions of cationic ruthenium biaryl thionolactone complexes

Bringmann, G.,Schoener, B.,Schupp, O.,Schenk, W.A.,Reuther, I.,et al.

, p. 275 - 284 (2007/10/02)

The preparations of novel thionolactone-bridged configuratively labile biaryls and their +-complexes are described.The dynamics of helimerization of these complexes and their reactivity towards nucleophiles have been investigated.Hydride transfer reagents lead to a cleavage ofthe thionolactone bridge to give the corresponding thiolate complexes, apparently via intermediate exothiolactolate ruthenium complexes.A similar lactolate analog is formed upon addition of a mild S-nucleophile.Key words: Ruthenium; Crystal structure; Thionolactone; Ring opening; Fluxionality

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