Cas 157620-35-4,C10H6(C6H2(CH3)2)(CSO)Ru(C5H5)(P(C6H5)2C2H4P(C6H5)2)(1+)*BF4(1-)=[C10H6(C6H2(CH3)2)(CSO)Ru(C5H5)(P(C6H5)2)2C2H4]BF4

157620-35-4

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Product Name: C₁₀H₆(C₆H₂(CH₃)2)(CSO)Ru(C₅H₅)(P(C₆H₅)2C₂H₄P(C₆H₅)2)⁽¹⁺⁾*BF₄^(1-)=[C₁₀H₆(C₆H₂(CH₃)2)(CSO)Ru(C₅H₅)(P(C₆H₅)2)2C₂H₄]BF₄
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CAS NO:157620-35-4
Molecular Formula:
Molecular Weight: 941.779
EINECS: N/A
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Chemical Properties

Melting Point: N/A
Boiling Point: N/A
Flash Point: N/A
Appearance: N/A
Density: N/A
Refractive Index: N/A
Storage Temp.: N/A
Solubility: N/A
CAS DataBase Reference: C₁₀H₆(C₆H₂(CH₃)2)(CSO)Ru(C₅H₅)(P(C₆H₅)2C₂H₄P(C₆H₅)2)⁽¹⁺⁾*BF₄^(1-)=[C₁₀H₆(C₆H₂(CH₃)2)(CSO)Ru(C₅H₅)(P(C₆H₅)2)2C₂H₄]BF₄(CAS DataBase Reference)
NIST Chemistry Reference: C₁₀H₆(C₆H₂(CH₃)2)(CSO)Ru(C₅H₅)(P(C₆H₅)2C₂H₄P(C₆H₅)2)⁽¹⁺⁾*BF₄^(1-)=[C₁₀H₆(C₆H₂(CH₃)2)(CSO)Ru(C₅H₅)(P(C₆H₅)2)2C₂H₄]BF₄(157620-35-4)
EPA Substance Registry System: C₁₀H₆(C₆H₂(CH₃)2)(CSO)Ru(C₅H₅)(P(C₆H₅)2C₂H₄P(C₆H₅)2)⁽¹⁺⁾*BF₄^(1-)=[C₁₀H₆(C₆H₂(CH₃)2)(CSO)Ru(C₅H₅)(P(C₆H₅)2)2C₂H₄]BF₄(157620-35-4)

Safety Data

Hazard Codes: N/A
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Safety Statements: N/A
WGK Germany:
RTECS:
HazardClass: N/A
PackingGroup: N/A
Hazardous Substances Data: 157620-35-4(Hazardous Substances Data)

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Check Digit Verification of cas no

The CAS Registry Mumber 157620-35-4 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 1,5,7,6,2 and 0 respectively; the second part has 2 digits, 3 and 5 respectively.
Calculate Digit Verification of CAS Registry Number 157620-35:
(8*1)+(7*5)+(6*7)+(5*6)+(4*2)+(3*0)+(2*3)+(1*5)=134
134 % 10 = 4
So 157620-35-4 is a valid CAS Registry Number.

157620-35-4Upstream product

157620-35-4Downstream Products

157620-44-5 (C₁₀H₆(C₆H₂(CH₃)2)(C(SCH₃)O)S)Ru(C₅H₅)(P(C₆H₅)2C₂H₄P(C₆H₅)2)

157620-35-4Relevant academic research and scientific papers

Synthesis and ring-opening reactions of cationic ruthenium biaryl thionolactone complexes

Bringmann, G.,Schoener, B.,Schupp, O.,Schenk, W.A.,Reuther, I.,et al.

, p. 275 - 284 (2007/10/02)

The preparations of novel thionolactone-bridged configuratively labile biaryls and their +-complexes are described.The dynamics of helimerization of these complexes and their reactivity towards nucleophiles have been investigated.Hydride transfer reagents lead to a cleavage ofthe thionolactone bridge to give the corresponding thiolate complexes, apparently via intermediate exothiolactolate ruthenium complexes.A similar lactolate analog is formed upon addition of a mild S-nucleophile.Key words: Ruthenium; Crystal structure; Thionolactone; Ring opening; Fluxionality

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