157836-52-7Relevant academic research and scientific papers
Rearrangements Studies on Acylketene O-Prop-2-ynyl S-Methylmonothioketals
Bhat, Laxminarayan,Ila, Hiriyakkanavar,Junjappa, Hiriyakkanavar
, p. 1749 - 1752 (2007/10/02)
Acylketene O-prop-2-ynyl S-methylmonothioketals 3a-e, easily obtained through displacement on β-oxosulfonium salts 2a-e by prop-2-ynol, are shown to undergo facile rearrangement under neutral (toluene-xylene) and basic conditions (K2CO3-EtCOMe) to afford
