15786-77-3Relevant academic research and scientific papers
Facile synthesis of enol ethers by cleavage of α-bromoacetals and α-bromoketals mediated by SmI2
Park, Heui Sul,Kim, Seong Ho,Park, Min Young,Kim, Yong Hae
, p. 3729 - 3732 (2001)
α-Bromocyclicacetals, α-bromocyclicketals and α-bromocyclicthioketals, derived from cyclic and acyclic ketones and aldehydes, reacted with samarium diiodide at -78°C in THF to furnish the corresponding enol ethers or thioenol ethers containing hydroxy or thiol moieties in high yields.
