157871-03-9

Basic information

• Product Name: 1,1-dimethyl-2-(phenylthio)silacyclopentane
• CAS NO: 157871-03-9
• Molecular Weight: 222.426
• Mol File: 157871-03-9.mol

Chemical Properties

• CAS DataBase Reference: 1,1-dimethyl-2-(phenylthio)silacyclopentane(CAS DataBase Reference)
• NIST Chemistry Reference: 1,1-dimethyl-2-(phenylthio)silacyclopentane(157871-03-9)
• EPA Substance Registry System: 1,1-dimethyl-2-(phenylthio)silacyclopentane(157871-03-9)

Safety Data

• Hazardous Substances Data: 157871-03-9(Hazardous Substances Data)

Upstream product

• 131473-01-3 1,1-Dimethyl-2-iodo-1-silacyclopentane 
• 108-98-5 thiophenol 

Downstream Products

• 157871-06-2 ((E)-6,6-Dimethyl-4-phenylsulfanyl-hept-4-enyl)-dimethyl-silanol 
• 157871-05-1 Dimethyl-((E)-4-phenylsulfanyl-non-4-enyl)-silanol 

Relevant articles and documents

Generation of 2-Lithio-2-(trimethylsilyl)silacyclopentane and 2-Lithio-2-(phenylthio)silacyclopentane and Their Use for the Synthesis of 1,4-Butanediols and γ-Hydroxy Ketones

Treatment of 2-(trimethylsilyl)silacyclopentane with t-butyllithium in THF-HMPA gave 2-lithio-2-(trimethylsilyl)silacyclopentane in good yield.An addition of alkyl iodides to the lithium compound provided 2-alkyl-2-(trimethylsilyl)silacyclopentanes which